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Akira Otoishi
Unlocked by beating Episode 3 of the Diamond is Unbreakable chapter in Story Mode
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Algol
Unlockable upon defeating him in Story Mode.
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Armor King
King's sub-boss, beat the game with him to unlock.
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Ay
AKA: A, Ei
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Azwel
AKA: Azwell
Final boss of Libra of Souls mode
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Baraka
Not available in Game Boy, Game Gear, or Master System versions.
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Ben Beckman
AKA: Benn Beckman
Initially exclusive to Red-Haired Shanks, later unlockable for all characters.
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Boxer
Create-a-character sample. Removed from the game with August 31, 2020 patch, although still accessible by rolling back to an earlier version.
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Burg
AKA: バーグ, Burger
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Cole MacGrath
Exclusive to PlayStation 3 and Vita versions. Guest character from Infamous series.
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D'bo
AKA: Devo (Japan)
Villain's side
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Duke
Unlockable by clearing the game with Alba and Soiree.
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Eagle
England, second opponent
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Eric O
Bosses gang, unlocked by beating Challenge Mode
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Fang
Available only in the Japanese Xbox version.
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Golden Luffy
AKA: Lucy
Obtainable by signing up for an account on the One Piece: Burning Blood website.
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