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Appule
Available only in the Japanese and PAL Wii versions.
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Azwel
AKA: Azwell
Final boss of Libra of Souls mode
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Beerus
Available after completing extra missions released via operator download at a later date.
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Blarney
Manual mentions a typing code to unlock, but method is unknown. Seemingly only accessible by tinkering with the XPR.INI file.
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Champa
Added to the game at a later date.
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Devil
AKA: Devil Kazuya
Complete all 8 stages in the Galaga mini-game to unlock
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Di-Amon
Playable in VS and Team modes only
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Eelis
AKA: Iris
Second boss, playable with code.
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Emperor Arkaneis
Final boss for Story Mode and Donner's Arcade Mode, secret final boss for everyone else's Arcade Mode. Unlockable upon beating Donner's Arcade Mode and Story Mode.
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Geezer
Final boss for "Angel" class characters.
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Kane
Unplayable at launch, free DLC later.
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Lucifer
AKA: Gilfer (Lucifer's final boss)
Third (final) boss, playable with code.
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Old Kai
AKA: Elder Kai, Rou Kaioushin
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Ooze Man
Playable by default in Versus and Link Modes.
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Sirou
Playable with code (only in versus mode)
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Supreme Kai
AKA: East Supreme Kai, Kaiōshin, Higashi no Kaiōshin
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Thanos
Unlockable in arcade with obscure operator code, more easily in ports.
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True Devil Kazuya
Potential final boss in Arcade Mode, penultimate fight and last "boss" type fight in Story Mode.
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