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Adon
AKA: Samson (2P)
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Armor King
King's sub-boss, beat the game with him to unlock.
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Ayane
Available only in Playstation version.
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Billy Thomas
Selectable by pressing either Circle or Cross on Jelly's portrait
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Boruto Uzumaki
Pre-order only character for regular edition of the game, or as part of the "Road to Boruto" pack.
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Champa
Added to the game at a later date.
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Dark Emi
AKA: Emi
Press Left, Left, Left, B, A, Start on the title screen to unlock her.
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Human Torch
Unavailable in Playstation Portable version.
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Jelly Thomas
Unlocked after completing Normal Mode with Kaiya
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